자연과학대학자연과학대학자연과학대학

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교원소개
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교수 및 연구

교원소개

Rohde, Jan-UweRohde, Jan-Uwe

연구분야

  • Coordination Chemistry, Organometallic Chemistry, Catalysis, Green Chemistry

연구내용

  • The Rohde group carries out fundamental research on the synthesis and chemistry of reactive transition metal complexes that is needed to design new synthetic and catalytic methods that utilize abundant and environmentally benign resources. Implementation of such methods in laboratory syntheses offers both environmental and economic advantages and may lead to the development of more sustainable industrial processes. Our interests in multi-electron redox transformations also intersect with chemistry relevant to biological processes and energy conversion.
  • Specific synthetic targets include i) organometallic complexes that activate small and inert molecules, ii) complexes of late transition metals in high oxidation states, and iii) complexes of redox-active ligands. Combining synthesis, structural analysis and mechanistic studies, the research in our group is multifaceted and offers students broad experience and training.

학력

  • Ph.D., Chemistry, University of Kiel
  • M.S., Chemistry, University of Kiel

주요경력

  • Faculty Member, UNIST
  • Faculty Member, University of Iowa
  • Post-Doc, University of Minnesota

대표논문

  • “Formation and reactivity of an (alkene)peroxoiridium(III) intermediate supported by an amidinato ligand”,
  • M. R. Kelley, J.-U. Rohde, Dalton Trans. 2014, 43, 527–537.
  • “Guanidinato Complexes of Iridium: Ligand-Donor Strength, O2 Reactivity, and (Alkene)peroxoiridium(III) Intermediates”,
  • M. R. Kelley, J.-U. Rohde, Inorg. Chem. 2013, 52, 2564–2580.
  • “The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide”,
  • J. J. Braymer, K. P. O’Neill, J.-U. Rohde, M. H. Lim, Angew. Chem. 2012, 124, 5472–5476; Angew. Chem. Int. Ed. 2012, 51, 5376–5380.
  • “Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2”,
  • M. R. Kelley, J.-U. Rohde, Chem. Commun. 2012, 48, 2876–2878.
  • “Reaction of an Oxoiron(IV) Complex with Nitrogen Monoxide: Oxygen Atom or Oxide(•1–) Ion Transfer?”,
  • T. M. Owen, J.-U. Rohde, Inorg. Chem. 2011, 50, 5283–5289.
  • “Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character”,
  • T. D. Manuel, J.-U. Rohde, J. Am. Chem. Soc. 2009, 131, 15582–15583.
  • “Stabilization of Iridium(IV) by Monoanionic Dialkyldiarylguanidinato Ligands”,
  • J.-U. Rohde, W.-T. Lee, J. Am. Chem. Soc. 2009, 131, 9162–9163.

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